Random Error

Using the utmost of care, the analyst can only obtain a weight to the uncertainty of the balance or deliver a volume to the uncertainty of the glass pipette. For example, most four-place analytical balances are accurate to $\pm 0.0001$ grams. Therefore, with care, an analyst can measure a $1.0000$ gram weight (true value) to an accuracy of $\pm 0.0001$ grams where a value of $1.0001$ to $0.999$ grams would be within the random error of measurement. If the analyst touches the weight with their finger and obtains a weight of $1.0005$ grams, the total and the random and systematic errors could be estimated to be $0.0001$ and $0.0004$ grams respectively. Note that the systematic error could be as great as $0.0006$ grams, taking into account the uncertainty of the measurement. Hence, taking several measurements of the $1.0000$ gram weight with the added weight of the fingerprint, the analyst would eventually report the weight of the finger print as $0.0005$ grams where the random error is still $0.0001$ grams and the systematic error is $0.0005$ grams. However, random errors set a limit upon accuracy no matter how many replicates are made.